Wax soo wadaban
18-Crow-Crow-6x; CS No.: 17455-13-9
Ereyo isku mid ah: 18-Criaret-6; 18-Craf-CPLE-6 Etherelen; okyleneeneene ok os oslide ceyrcle chaclil chacamer hexamer.
Hantida kiimikada ee 18-Crow-6
● Imaanshaha / Midabka: Si qalad ah oo adag
● Cadaadiska uumiga: 4.09E-06mmhg at 25 ° C
● dhibic dhalaal ah: 42-45 ºC (iftiinka.)
● Index nooleenta ah: 1.404
● Meel karkaraya: 395.8 ºC 760 mmhg
● Flash dhibic: 163.8 ºC
Psa Psas:55.38000
● cufnaanta: 0.995 g / cm3
● LOGP: 0.09960
● Kaydinta ku keydinta ah: at 0-5 ° C
● Xasaasiyadda.fyGroscopic
SOLUBLENT.:CHLOBOBOMB (waxyar), methanol (aad u yar)
● Xoolaha biyaha ..Sooluluble
● Xlogp3: -0.7
● Ku tabaruca haynta deganaanshaha hydrogen-ka ah tirinta: 0
● Aqbalida debaajiga debaajiga ah: 6
● Tirinta denbiyada la rogayo: 0
● sax ah tiro: 264.15728848
● Tirinta culus ee atomka: 18
Isku-duwaha: 108
Macluumaadka SAFT
● Sawirada (yada):
Xn,
XI
● Koodhadhka Hazard: Xn, XI
● Weedhaha: 22-36 / 37 / 38-36-36-20 / 22-20 / 21/22
● Hadafyada badbaadada: 26-36-39
Waxtar leh
Fasalada kiimikada:Fasalada kale -> Xeeruudaha kale ee dabiiciga ah
Dhoola cadeynta canonical:C1coccoccoccoccoccoccoccoccocco
Adeegsiga:Xaraashka wareejinta wejiga ee waxtarka leh. 18-Crow-6 waxaa loo isticmaalaa sidii wajiga wareejinta wajiga oo hufan iyo wakiil murugsan oo leh noocyo yar oo yar yar. Waxay ku lug leedahay isku-darka isku-darka ah ee ku saabsan Waxay fududeynaysaa xariigashada Khudssium Kepassium ee Benzene, oo loo isticmaalo in lagu xuso xeryaha dabiiciga ah. Waxaa loo isticmaalaa in lagu dardar geliyo falcelinta kaladuwan ee kaladuwan iyo sidoo kale waxay sare u qaadeysaa awoodda nucleophiles sida potassium-ka acetate. Waxaa loo adeegsadaa falcelinta alklation-ka markii uu joogaa kaarboon potassium, n-alklation of clutarimimeitide iyo sumcibimide oo leh Diththylcharbonate. Dhismaha uu sameeyay falcelintiisa ee cyanide potassium-ka wuxuu ku dhaqmayaa sidii wax u dhexgala sida cyanosis-ka ee aldevydes, kefiies iyo quines leh trimethylside (TMSCN). 18-I-Crow-6 ayaa loo isticmaali karaa in lagu dhajiyo n-alkalation of xeryahooda heterocyclic-ka iyo albexydes-ka firfircoon.
Hordhac faahfaahsan
18-CPR-6Waa xarun cotclic ah oo kale oo leh qaaciddada kiimikada C12H24O6. Waxaa loo magacaabaa "18-CP-6" maxaa yeelay waxay ka kooban tahay giraan ah lix atam oo oksijiin ah, oo sameysma qaab dhismeedka u eg '', oo ay leedahay 18 atom oo kareeg ah guud ahaan. Waa midab aan midab lahayn, crystalline-ka adag oo ku dhex milma xayeysiinta dabiiciga ah laakiin wax yar oo biyo ah.
Magaca "taaj" waxaa laga soo qaatay isu-ekaanta qaabdhismeedka xarunta ee taaj sababta oo ah lixda atamka oksijiin ee loo habeeyay qaab wareeg ah. Qaab-dhismeedkan qaaska ah wuxuu siinayaa 18-CP-6-6-da-ah oo gaar ah waxayna awood u siineysaa in si ballaaran loogu isticmaalo codsiyada kala duwan.
Mid ka mid ah astaamaha ugu muhiimsan ee 18-chop-6 waa awoodeeda ay ku adag tahay cakiran ionga birta ah. Atamka oksijiinka ee giraan taajka ah ayaa isku dubbaridi kara birta birta ah, sida potassium, sodium, ama kaalshiyam, si loo sameeyo isku dubbarid isku dubbarida xasilloon. Hantidan wuxuu sameeyaa 18-chop-6-6-da-a
Isticmaal
Isku-dhafka ionga ion ee 18-chop-6 wuxuu yeelan karaa dhowr codsi:
XUQUUQDA MADAXWEYNAHA:Sida Benzyttrimethyltheretyromylommlomium chloride, 18-chop-6 wuxuu sidoo kale u dhaqmi karaa sidii wax xajin kara wajiga. Waxay ka caawisaa wareejinta noocyada lagu soo eedeeyo, sida ionyada birta, inta udhaxeysa wejiyada aan la duminin, taasoo awood u siineysa falcelinta haddii kale adkaan laheyd ama aan macquul aheyn. Crown daloolka suufka ah ayaa awood u leh inuu taari karo birta birta ah, taasoo u oggolaaneysa inay ka gudbaan xuub ama wareejinta inta u dhexeysa dareeraha kaladuwan.
Soosaarka ion ion ion iyo kala goynta:18-Crow-6 waxaa badanaa loo adeegsadaa farsamooyinka soo saarista si loo xusho si xulasho ah oo si gaar ah loo soosaaro iyo ion gaar ah oo bir qaas ah oo ka soo baxa isku-dhafka isku dhafan. Awooda ay u leedahay inay ku xidho macdanta birta qaarkood waxay u oggolaaneysaa go'doominta iyo nadiifinta ionyadan isku dar ah.
Aqoonsiga ion iyo dareenka:Isku-dhafka ionga ion ee 18-chop-chop-6 waxaa lagu isticmaali karaa qaabeynta dareemayaasha kiimikada iyo ion-xulashada elektrodes. Adigoo ku daraya 18-Crow-Conf-6 galay nidaamyada dareeraha, waxaa suurtagal ah in si xushmad leh loo ogaado loona cabbiro ions bir ah oo gaar ah oo ku saleysan xiriirkooda xaga xidhiidhkooda.
Nidaamyada gaarsiinta daroogada:Awoodda 18-------ka-6 si loo sameeyo dhismeyaal ay ku jiraan ions bir ah ayaa lagu isticmaali karaa nidaamyada dhalmada daroogada. Adigoo ka reebay ion ionga bir bir ah oo ka dhex jira daloolka ether ee weyn, waxaa suurtagal ah in la ilaaliyo ionga birta inta lagu gudajiro gaadiidka oo lagu sii daayo hab la xakameeyay goobta bartilmaameedka.
Guud ahaan, 18-Croom-6 waa xarun iskuxiran oo ku saabsan codsiyada ku saabsan casaaradka wejiga, soo saarista ion ee ion, ion ictiraafka, iyo dhalmada daroogada. Qaab dhismeedkeeda Ether ee u gaarka ah ee loo yaqaan 'Ether Ether Ether' iyo guryaha kakadu waxay ka dhigeysaa aalad qiimo u leh qaybaha kala duwan ee kimistariga iyo sayniska alaabada.
