Diikenzo-18-CPE-CEPR-6; CS No.: 14187-32-7 Sawirka muuqaalka

Diikenzo-18-Crown-CP-6; CS No.: 14187-32-7

Sharraxaadda Gaaban:

Magaca kiimikada:Digenzo-18-Chop-6
CAS MAYA:14187-32-7
Hoos udhacay CAS:5476-16-16-16-16-16-16-1617-310,66105-26-83188-7318-69318-693172-3918-4,610,66105-26-83128-69-5-5
Qaaciddada molikaulal:C20h24o6
Miisaanka Moleculal:360.407
HS Code:29329995
Lambarka Bulshada ee Yurub (EC):238-041-3
NSC lambarka:147771
UNII:0a7W45JCS9
Aqoonsiga walax ee DSstox:Dtxssiid6022428
Nambarka nikkaji:J14.747h
Wikipedia:Digenzo-18-Chop-6
Wikidata:Q5272256
Metabolomics Workbench ID:52751
Chexbal ID:Chemfl345536
Faylka MOL:14187-32-7.mol

U dir emaylka

Si faahfaafo

Calaamadaha wax soo saarka

Ereyo isku mid ah: diibenzo-18-chop-chop-6; polyether 'XxVIII

Hantida kiimikada ee Digenzo-18-CP-6

● Imaanshaha / Midabka: White to wax yar oo budada beige fluffy
● Cadaadiska uumiga: 3.65E-10MMHG 25 ° C
● dhibic dhalaal: 162-164 ° C (iftiinka.)
● Index laysidoodu ku jiro: 1.5
● Meel karkaraya: 503.1 ° C 760 mmhg
● Flash Point: 206 ° C
Psa Psas:55.38000
● cufnaanta: 1.108 g / cm3
● Leein: 2.94880

● Kaydinta ku meel-gaarka ah ee ka hooseeya + 30 ° C.
● xasaasiyad.
SO SO SO SO SO SOLUBLEL.:0.007G/L
SOLDITITITITITITITITITES.:SPARESPARYLE
● Xlogp3: 2.2
● Ku tabaruca haynta deganaanshaha hydrogen-ka ah tirinta: 0
● Aqbalida debaajiga debaajiga ah: 6
● Tirinta denbiyada la rogayo: 0
● sax ah tirada saxda ah: 360.15728848
● Tirinta culus ee atomka: 26
Isku-duwaha: 300

Macluumaadka SAFT

● Sawirada (yada):XI,Xn
CODSASAHA GUUD: xi, xn
● Weedhaha: 36-36 / 37 / 38-20 / 21/22
● Weedhaha amniga: 26-37 / 39-36

Waxtar leh

Fasalada kiimikada:Fasalada kale -> Xeeruudaha kale ee dabiiciga ah
Dhoola cadeynta canonical:C1coc2 = cc = cc = c2occoccoc3 = cc = cc = c3occo1
Adeegsiga:Digenzo-18-Crown-CP-6, waxaa loo istcimaalaa sidii wax muhiim ah oo ceyriin ah iyo mid dhexe oo muhiim ah oo lagu isticmaalo isku-darka dabiiciga ah, dawooyinka, hawo-mareennada iyo Dyrochemicaf. Waa mid dhexdhexaad ah oo dabiici ah. Crown Ether / Diirenzo-18-Crow-CP-6 ee isku-darka. CAS 14187-32-7, Mashiinka Mashiinka 360.41 g / mol.

Hordhac faahfaahsan

Digenzo-18-Chop-6, sidoo kale loo yaqaan DB18c6, waa mid soo jiidasho leh 18-CIP-6 oo ay ka kooban tahay laba giraan oo benzene ah oo ku lifaaqan qaab dhismeedka ether ether ah. Waa xarun cotclic ether ah oo leh qaaciddada kiimikada C20h24o6. Ku darista Benzenene giraangirta 18--CIP-6 waxay kor u qaadaa xasilloonideeda waxayna xoojisaa guryaheeda, samaynta Diilvo-18-CP-6-CP-6 xarun gaar ah oo leh astaamo gaar ah.
Joogitaanka fardaha Benzene ee ku yaal Diyvo-18-CP-CPE-6 ayaa ku soo bandhigaya Arooska Molecule, kaasoo si weyn saameyn ugu yeelan kara guryaha kiimikada iyo jir ahaaneed. Ku darista sinjiifkan ayaa kor u qaadaya elektroonikada gudaha molecule-ka, samaynta Diigdo-18-Chop-6-ka-adag oo dabacsan oo dabacsan marka loo eego xarun waalidkiis, 18-Crow-6.
Hordhac ku saabsan moreties udgoon ee Digenzo-18-CP-6 ayaa sidoo kale beddelaya xalihiisa iyo xidhiidhkeeda dareeraha kaladuwan. Wax ka beddelkan ayaa inta badan horseedaa jilicsanaanta xargaha xargaha xubnaha dabiiciga ah, sameynta Digenzo-18-Crow-CP-6 ku habboon codsiyada kala duwan ee u baahan nidaamyada aan-u-dafka ahayn ama udgoonnada.
Waxay lamid tahay 18-Chopenzo-6, Diisenzo-18-CPE-CEPR-6 waxay ku haysataa awoodda ay ku adag tahay ionshadda birta ah, sameynta isku dubbarid isku dubbarida xasilloon. Jiritaanka giraanta benzene waxay sii xoojin kartaa xulashada iyo xasilloonida ee dhismayaasha birta, oo ka dhigaya distenzo-18-Crow-CP-6 waxtar leh soo saarista ion, kala tagga, iyo casaaradka, iyo casaaradka, oo la mid ah xarunta waalidka.
Digenzo-18-Crown-CP-6 ee loo xoojiyay Dive-6-da-6 ee loo xoojiyay ayaa sidoo kale ka dhigaya mid u adkaysata u adkeysiga xaalada kuleylka marka loo barbar dhigo 18-Crown-6. Muuqaalkaani wuxuu gacan ka geystaa codsigiisa falcelinta heerkulka iyo howlaha.
In kasta oo ayikenzo-18-Chop-6 Saamiyada ay la mid tahay 18-CP-6, guryahooda u gaarka ah waxay u dhigantaa xarun qiimo badan oo loogu talagalay codsiyada kaladuwan ee kimistariga, soo saarista dareeraha, ion dareenka, casaaradka, iyo habraaca heerkulka. Ku darista geedaha Benzene ee qaab dhismeedka Ether Ether wuxuu kor u qaadayaa deganaanheeda, waxay wax ka beddeshaa astaamaha lafaha, waxayna ku fidisaa suurtagalnimadeeda ay ku adeegsan karto qaybaha kala duwan ee kimistariga iyo sayniska.

Isticmaal

Diikenzo-18-Crown-CP-6 (DB18C6) waxay leedahay dhowr dalabyo kala duwan oo ku saabsan beero kala duwan, oo ay ku jiraan:
Soosaarka ion ion ion iyo kala goynta:DB18C6 aad ayey waxtar ugu leedahay kakadaasida ionshada birta. Awooda ay u leedahay inay si xushmad u leedahay iyada oo ay ku dhejiso ion-ka birta sida sodium, potassium, iyo ammonium-ka ayaa waxtar u leh soo saarista ion birta iyo geedi socodka kala go'ida. Waxaa loo shaqaysan karaa farsamooyinka soosaarka ee xallinta si loo soo xusho ion gaar ah oo bir ah oo ka soo baxa.
Chemistry-ga supromicalar:DB18C6 waxaa si weyn loogu isticmaalaa kimistariga supramolecaular. Qaab-dhismeedkeeda u gaarka ah iyo dhismaheeda u gaarka ah waxay ka dhigtaa sameynta martida martida-martida leh ee leh moleekuleyaal badan oo martida ah, oo ay ku jiraan xeryahooda yar yar iyo ion. Is dhexgalkaan martida martida loo yaqaan 'martida' waxaa loo isticmaali karaa naqshadeynta iyo dhismaha nidaamyada molika ee shaqeeya iyo qalabka.
Naasaha ion:Sababta oo ah qaabdhismeedka Ether ee Crown, DB18C6 waxay si buuxda ugu xidhiidhi kartaa ion, taasoo horseedaysa isbeddelo ku saabsan indhaha, kontoroolka guryaha, ama guryaha fallaadhka ah. Hantidani waxay ka dhigeysaa DB18C6 shey qaali ah oo dareenka ah, kaas oo laga shaqeyn karo horumarinta dareemayaasha ion iyo qalabka wax lagu baaro.
Cancsis:DB18C6 iyo dhismaheeda Ion ee birta ah waxay u dhaqmi karaan sidii wax soo saar ah falcelinno kala duwan. Qaabkooda u gaarka ah waxay bixiyaan jawi ku habboon fududeynta isbedelada kiimikada gaar ah. DB18C6-ku-saleysan-ku-saleysan ayaa loo shaqeeyey isku-darka dabiiciga ah, falcelinta oksikada, iyo geedi socodka kale ee danta.
Geedi socodka heerkulka-sare: xasilloonida la xoojiyay iyo iska caabinta iyo nabaad-guurka kuleylka ee DB18c6 marka la barbar dhigo 18-CP-6 ayaa ku habboon in codsiyada loo baahan yahay heerkulka heerkulka. Waxaa loo adeegsan karaa falcelin heerkulka-sare, oo ay ku jiraan polymomanemization, isku-darka dabiiciga ah, iyo geedi socodka kale ee heerkulka.
Nidaamyada dareeraha qalooca: Sida hore loo soo sheegay, soo bandhigida fardaha Benzene ee DB18c6 waxay wanaajisaa xalideeda xalidooda nidaamyada aan loo qaadin ama udgoon. Hantidan ayaa ka dhigaya xarun waxtar leh oo loogu talagalay codsiyada u baahan kala diridda jawi qaas ah.
Guud ahaan, qaab-dhismeedka gaarka ah iyo astaamaha DB18c6 U oggolow codsiyo fara badan oo kala duwan kimistariyada isku-duwidda, kimistariga jir, ion dareenka casaarashada, casaaradka, iyo habraaca heerkulka. Awoodda ay u leedahay inay si ula kac ah ula macaamilaan moleekuleyaal kala duwan iyo ion-ka birta waxay ka dhigeysaa xarun qiimo leh dhowr cilmi-baaris iyo warshado warshadeed.